Step right up for bigger 2D sheets

Rice theory shows how monocrystals of hexagonal boron nitride come together

Very small steps make a big difference to researchers who want to create large wafers of two-dimensional material.

Atom-sized steps in a substrate provide the means for 2D crystals growing in a chemical vapor furnace to come together in perfect rank. Scientists have recently observed this phenomenon, and now a Rice University group has an idea why it works.

Rice materials theorist Boris Yakobson and researcher Ksenia Bets led the construction of simulations that show atom-sized steps on a growth surface, or substrate, have the remarkable ability to keep monolayer crystal islands in alignment as they grow.

If the conditions are right, the islands join into a larger crystal without the grain boundaries so characteristic of 2D materials like graphene grown via chemical vapor deposition (CVD). That preserves their electronic perfection and characteristics, which differ depending on the material.

The Rice theory appears in the American Chemical Society journal Nano Letters.

– See more at Rice News

Print Friendly, PDF & Email

Leave a Reply

Your email address will not be published. Required fields are marked *